Ron Tuinstra [Illiana Christian High School, Chemistry]
The Concept of the Mole
Ron brought in a roughly square piece of galvanized iron
(iron with a zinc coating) about 2.5 cm on a side and 1 mm
thick. He weighed and measured the piece, and then removed the zinc from
it by soaking it in hydrochloric acid: Zn + 2 HCl ®
ZnCl2 + H2 (bubbles) After the chemical
reaction had ceased, he thoroughly washed the piece in water, and then dried
it. The metallic piece was visibly thinner than it had been.. Our objective was to determine the approximate number of zinc atoms on
the piece of galvanized iron, and the approximate thickness -- in atoms -- of the zinc
coating. The procedure involves measuring the mass and size of the
galvanized iron, before and after the zinc coating is removed. From the
masses of zinc and iron, we can calculate the number of moles and atoms of each
metal. By using the known radius of the zinc atom and assuming that the
atoms of zinc are stacked directly on top of each other in the coating, we can
estimate the thickness of the coating.
We took data and made calculations concerning the piece of galvanized iron, as given in this table:
Length of rectangle | 2.5 cm |
Width of rectangle | 2.6 cm |
Mass of rectangle (before acid treatment) | 2.40 gm |
Mass of iron core / Fe (after acid treatment) | 2.18 gm |
Mass of zinc coating / Zn | 0.22 gm |
Molar mass of Fe | 55.8 gm/mole |
Num moles of Fe in sample | 3.9 ´ 10-2 moles |
Molar mass of Zn | 65.38 gm/mole |
Num moles of Zn (in original coating) | 3.4 ´ 10-3 moles |
Mole ratio: Zn/Fe | 0.086 |
Num Zn atoms | 2.0 ´ 1021 |
Num Fe atoms | 2.4 ´ 1022 |
Mass of Zn / one side | 0.11 gm |
Density of Zn | 7.14 gm/cm3 |
Volume of Zn /one side | 1.5 ´ 10-2 cm3 |
Thickness of Zn coating | 2.4 ´ 10-3 cm |
Size of Zn atom | 2.66 ´ 10-8 cm |
Thickness of Zn (in atoms) | 85,000 atoms |
Chris Etapa [Gunsaulas Academy]
Energy Ball!
Chris brought in an Energy Ball [http://www.stevespanglerscience.com/product/1406], which she
uses for
teaching about electrical circuits. The Energy Ball resembles a ping-ping
ball, with two metallic contacts on its surface, as well as a battery, a
light bulb, and a "beeper" hidden inside. When the contacts
are connected, the light goes on and the beeper sounds, signaling that
a circuit has been completed! When one of us put our thumb on one of the
contacts and our forefinger on the other one, the light and sound again were
produced. Next one person touched one contact and another person touched the other contact.
Nothing happened -- until the two people
touched their hands together -- again! -- light and sound!. We then
formed a "human chain" with several people holding hands When the two
people at the ends of the chain each touched the contacts as before -- sound
and light! When the human chain was broken, the signal stopped
abruptly. Remarkable, but how come? Pat Riley and Ben Stark pointed
out that there is saltwater on our skins, and electrolyte solutions throughout
our bodies, which are fairly good conductors of electricity. A small
amount of electricity is conducted by our bodies, completing the circuit and
triggering the sound and light from the ball. These human circuits are similar, in
principle, to circuits involving metallic wires.
Fascinating stuff, Chris!
Larry Alofs [Kenwood HS, Physics]
Flame Tests!
A visitor from the Math-Physics SMILE class, Larry
showed that flame tests provide a means of identification of materials. He
had a supply of small "nasal spray" bottles that contained solutions of
various ions and salts, as well as a portable torch.
Larry lit the torch, and then he sprayed a tiny cloud of one of the solutions directly
into the flame. We could easily see the flame change to a color that was distinctive of the
alkali / alkaline metal (lithium, sodium, potassium, calcium, etc) in the
solution, which lasted for a few seconds before disappearing. Sodium, for
example, produces a yellow-orange flame color; potassium
produces red. Every minute or so he sprayed a different chemical into the
flame,
producing a new color. The effect was especially dramatic when we
turned out the lights in the room. These spray bottles produce a fine mist
of the solution, which works very well for doing flame tests.
You really set things on fire! Thanks for popping in and showing us how to do this, Larry.
Notes taken by Benjamin Stark