Surface Tension of Water
Barbara Pawela                  Retired
                          
Objectives:
  1.  To use the phenomenological approach to demonstrate the basic concepts 
       associated with surface tension.
  2.  To demonstrate the meaning of adhesion.
  3.  To demonstrate the meaning of cohesion.
  4.  To determine the relationship between the molecular attraction, adhesion,
       cohesion, and surface tension.
  5.  To show that surface tension plays an important role in detergents and 
       other cleaning agents.
Materials Needed:
      water                aluminum foil               index cards
      alcohol              marbles or paper clips      scissors
      dish detergent       wire mesh                   talcum powder
        or chips of soap   waxpaper                    different light-weight
      bubble solution      small jars                    materials            
      bubble blowers       plastic glasses
Strategies:
                   
Activity I:
  1.  Divide the class into groups of 4 or 5 students.  Have stations set up for 
      the different activities.  
  2.  At each station, have 2 plastic glasses filled to the brim with water. 
      Have a pre-measured container of water from which a student from each 
      group extracts water with an eye dropper, and transfers it drop by drop to 
      one of the above-mentioned plastic glasses.  Have the students predict 
      what might happen.  As the activity to overfill the glass continues, have 
      the students observe that very many drops of water can be added without 
      the water spilling out.  If done carefully, the water forms an oval shape 
      above the rim of the glass.  Continue putting in the drops of water until 
      the water starts spilling out of the glass.  Check the amount of water 
      that was used by calculating the difference in the amount of water left in 
      the pre-measured container. 
  3.  Next, have another student in each group use marbles or paper clips to 
      overfill the other plastic glass in the same manner described above. 
      Discuss with the students what they observed and elicit responses about 
      what the possible causes were of what they observed. 
  4.  Review with the students the concept of the molecule as a single unit of a 
      completed whole.  Use an example such as a brick being a single unit in 
      building the exterior of a brick house.  
  5.  Introduce the term "surface tension" of water.  Explain to the students 
      that surface tension of water is caused by the attraction of the water 
      molecules for each other.  Use a magnet to attract some steel paper clips 
      and similar objects to get the idea of attraction across to the students. 
      Discuss and conclude that this attraction that the molecules have for each 
      other is particularly strong on the surface of the water, because the 
      molecules have nothing above them to be attracted to, so they pull harder 
      to the sides and down.  This pulling creates a "skin" or  film on the 
      surface.  The film on the surface is pulled tightly over the liquid. 
      Surface tension refers to the fact that the surface of the liquid water is 
      pulled tightly together by attractions from inside. 
 
Activity II:
  1.  At each station have a sheet of wax paper, and an eye dropper.  Have one 
      student in each group put three drops of water near, but not touching, 
      each other.  Have another student use a toothpick to gently push the water 
      drops toward each other.  Discuss what was observed.  The drops were 
      attracted to each other and formed a single drop.  After a few minutes, 
      the drop flattened because of the effect of gravity. 
  2.  Have another group member place another drop of water on the wax paper. 
      Observe what happens in the next few minutes to the drop.  Discuss and 
      conclude that the water drops seem to want to come and stick together. 
      There seems to be a force that keeps the water together.  Explain that 
      this force is called cohesion.  
Activity III:
  1.  For each group have 2 basin-like dishes filled with water.  Sprinkle 
      talcum powder lightly on the surface of the water.  Have a student    
      squirt one drop of alcohol onto the talcum powder in one of the dishes. 
      The talcum powder will move away from where the alcohol drop fell.  Have 
      another student use a small piece of wet soap and touch it to the water 
      near the edge of the other dish.  The talcum powder will move to opposite 
      side of the plate.  Discuss and conclude that the alcohol and the soap 
      weakened the surface tension of the water at one point and the increased 
      surface tension on the other part of the water contracts the surface and 
      pulls the talcum powder with it. 
  2.  Give each group an index card and have them draw an isosceles triangle and 
      cut it out.  This will be their boat.  Have a  dishpan or similar 
      container filled with water.  Have the students place the boat on the 
      water and let it float.  Have the students put a small drop of dish-
      washing liquid on their finger.  Instruct the students to dip their finger 
      in the water behind their boat.  The boat moves forward.  Discuss and 
      conclude that the soap weakened the surface tension behind the boat.  
      Because the  surface tension was stronger in front of the boat, the boat 
      was moved forward.  The weakening of surface tension occurs because the 
      soap molecules move between the water molecules and weaken their 
      attraction for one another.  As a result cohesion of the water becomes 
      less and surface tension decreases. 
  3.  Put some water in a jar.  Pour a small amount of cooking oil on the water. 
      Mix the oil and water.  Have the students  observe what happens.  The oil 
      forms drops that gather together.  Add a few drops of the dish-washing 
      detergent to the jar and mix.  The oil seems to mix with the water. 
      Discuss and have students give hypotheses for what they observed.  Explain 
      to the students that surface tension plays a very important part in the 
      action of soaps and detergents.  When oil is poured on water it has a 
      strong surface tension.  The water also has a strong surface tension.  The 
      adhesion between the oil and water is weak.  The water pulls toward itself 
      and the oil pulls toward itself.  They do not mix.  When the detergent is 
      added to the oil and water, one end of each molecule of detergent is 
      attracted to water molecules.  The other end is attracted to oil 
      molecules.  The detergent molecule forms a kind of bridge of attraction 
      between the water and oil molecules. 
     
Reference: 
    
    Don Herbert and Hy Ruchlis Mr. Wizard's 400 Experiments in Science, 
        Copyright, 1968, Book Lab Publisher 
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